Characteristic of Thermocouples

characteristics
thermocouples
general composition temperature
range
suitable
application
unsuitable application
type E base metal thermocouple
NiCr - CuNi (nickel-chrome/
copper-nickel)
single wires made of
non precious metals
EP-leg: 89-90% nickel, 9-9.5% chrome, 0.5% silicium and iron, balance: C, Mn, Nb, Co

EN-leg: 55% copper, 45% nickel, approx. 0.1%, co balt, iron and manganese
-200°C/+700°C •  in pure, oxidizing (air) or neutral atmosphere (inert gases)
•  high resistance against corrosion
•  small thermal conductivity
•  do not apply in sulphuric, reducing or alternately oxidizing and reducing atmosphere
•  do not apply in vacuum for a long time
type J base metal thermocouple
Fe - CuNi (iron/copper-nickel)
single wires made of
non precious metals
JP-leg: 99.5% iron, approx. 0.25% manganese, approx. 0.12% copper, balance: other impurities

JN-leg: 55% copper, 45% nickel, approx. 0.1%, co balt, iron and manganese
-180°C/+700°C •  from 0 - +760°C in vacuum, oxidizing (air), reducing or inert atmosphere (inert gases) •  temperatures below 0°C
•  sulphurous atmosphere above +500°C
•  above +760°C only with bigger wire diameters
type K base thermocouple
NiCr - NiAl (nickel-chrome/
nickel-aluminum)
single wires made of
non precious metals
KP-leg: 89-90% nickel, 9-9.5% chrome, 0.5% silicium and iron, balance: C, Mn, Nb, Co

KN-leg: 95-96% nickel, 1-1.5% silicium, 1-2.3% aluminum, 1-3,2% manganese, 0.5% cobalt, balance: Fe, Cu, Pb
-270°C/+1372°C •  from +250°C - +1260°C in pure, oxidizing (air) and neutral atmosphere (inert gases)
•  for higher temperatures bigger wire diameters are recommended
•  between +250°C up to +600°C not suitable for exact measurements with quick temperature changes
•  not appropriate for a longer time with high temperatures in vacuum
•  do not apply with high temperatures in sulphurous, reducing or alternately oxidizing and reducing atmosphere without protection
•  do not use in atmosphere prone to “green mold”
type L base thermocouple
Fe - CuNi (iron/copper-nickel)
single wires made of
non precious metals
LP-leg: 99.5% iron, approx. 0.25% manganese, approx. 0.12% copper, ballance: other impurities

LN-leg: 55% copper, 45% nickel, approx. 0.1% cobalt, iron and manganese
0°C/+900°C •  from 0°C - +760°C in vacuum, oxidizing (air), reducing or inert atmosphere (inert gases)
•  above +500°C bigger wire diameters are recommended
•  temperatures below 0°C
•  sulphurous atmosphere above +500°C
•  above +760°C only with bigger wire diameters
type N base thermocouple NiCrSi - NiSi
(nickel-chrome-silicium/
nickel-silicium-magnesium)
single wires made of
non precious metals
NP-legl: 84% nickel, 14-14.4% chrome, 1.3-1.6% silicium,
ballance (not more than 0.1%): Mn, Fe, C, Co

NN-legl: 95% nickel, 4.2-4.6% silicium,  0.5-1.5% magnesium,
ballance: Fe, Co, Mn, C, (altogether 0.1-0.3%)
-270°C/+1300°C •  from +300°C - +1260°C in pure, oxidizing (air) and neutral atmosphere (inert gases) •  do not use with high temperatures in sulphurous, reducing or alternately oxidizing and reducing atmosphere without protection
•  do not use with high temperatures in vacuum
•  do not use in atmosphere with “green mold”
•  reducing atmosphere
type R base thermocouple
Pt13%Rh - Pt (platinum
13% rhodium/platinum)
single wires made of platinum
and platinum-rhodium alloy
RP-leg: platinum with 99.99% purity with a rhodium alloy (purity 99.98%) 13±0.05% rhodium portion

RN-leg: platinum with 99.99% purity
-50°C/+1768,1°C
(melting point)
recommended:
up to +1300°C
•  pure, oxidizing atmosphere (air), non aggressive (inert-) gases and short-term in vacuum
•  above +1200°C type B more appropriate
•  reducing atmosphere
•  metal gases (for example plomb or zinc)
•  aggressive vapors containing arsenic, phosphor or sulphur
•  do never use metal protecting tubes with higher temperatures
•  sensitive against impurities of impure metals
type S base thermocouple
Pt10%Rh - Pt (platinum
10%rhodium/platinum)
single wires made of platinum
and platinum-rhodium alloy
SP-leg: platinum with 99.99% purity with a rhodium alloy (purity 99.98%) 10±0.05% rhodium portion

SN-leg: platinum with 99.99% purity
-50°C/+1768,1°C
(melting point)
recommended:
up to +1300°C
•  pure, oxidizing atmospheres (air), non aggressive (inert-) gases and short-term in vacuum
•  above +1200°C type B more appropriate
•  reducing atmosphere
•  metal gases (for example plomb or zinck)
•  aggressive vapors containing arsenic, phosphor or sulphur
•  do never use metal protecting tubes with higher temperatures
•  sensitive against impurities of impure metals
type B base thermocouple
(Pt30%Rh - Pt6%Rh platinum -
0% rhodium/
platinum-6% rhodium)
single wires made of platinum
and platinum-rhodium alloy
BP-leg: platinum with 99.99% purity with a rhodium alloy (purity 99.98%) 29.60±0.2% rhodium portion

BN-leg: platinum with 99.99% purity with a rhodium alloy (purity 99.98%) 6.12±0.02% rhodium portion
max. +1820°C
(melting point)
ordinary up to
+1700°C
•  pure, oxidizing atmosphere
•  neutral atmospheres
•  vacuum
•  reducing atmosphere or such with aggressive vapors or impurities which react with metals of the platinum group, if it isn’t protected with a non metal protecting tube
type T base thermocouple Cu - CuNi
(copper/copper-nickel)
single wires made of
non precious metals
TP-leg: 99.95% copper, 0.02-0.07% oxygen, 0.01% impurities

TN-leg: 55% copper, 45% nickel, approx. 0.1% cobalt, iron and manganese
-270°C/+400°C •  from -200°C - +370°C in vacuum, oxidizing (air), reducing or inert atmosphere (inert gases)
•  with higher temperatures bigger wire diameters are recommended
•  above +370°C not appropriate in a hydrogen atmosphere
•  not appropriate in radioactive environment
type U base thermocouple
Cu - CuNi
(copper/copper-nickel)
single wires made of
non precious metals
UP-leg: 99.95% copper, 0.02-0.07% oxygen, 0.01% impurities

UN-leg: 55% copper, 45% nickel, approx. 0.1% cobalt, iron and manganese
0°C/+600°C
(+400°C)
•  from -200°C - +370°C in vacuum, oxidizing (air), reducing or inert atmosphere (inert gases)
•  with higher temperatures bigger wire diameters are recommended
•  above +370°C not appropriate in a hydrogen atmosphere
•  not appropriate in radioactive environment

Abbreviations: C= carbon, Mn= manganese, Nb=niobium, Co=cobalt, Fe= iron, Pb=plomb, Cu=copper CuNi is also called Constantan®